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class="product-short-sum">脫硫概述<br/>SO2作為影響大氣質(zhì)量最主要的氣態(tài)污染物之一，一般是通過(guò)燃料燃燒和工業(yè)生產(chǎn)過(guò)程產(chǎn)生的。它不僅對動(dòng)植物產(chǎn)生損害，而且是引起酸雨、光化學(xué)反應和溫室效應的主要物質(zhì)之一，另外對人類(lèi)的呼吸系統有很強的刺激性、損害性。<br/>為了降低SO2的排放濃度，在控制燃料含硫量、燃料燃燒方式等方法之外，依然以脫硫方法為主。當前脫硫主要分為兩類(lèi)，既濕法脫硫與干法脫硫兩種。<br/>干法脫硫：使用粉狀、粒狀吸收劑去除廢氣中的SO2。<br/>濕法脫硫分為：主要分為鈣法脫硫、雙堿法脫硫、氨法脫硫等。</div> </div> <div id="8uwwqwm" class="prd_detInfo_con"> <div id="o80oues" class="product-properies-groups"> </div> </div> </div> <div id="gc0cya0" class="clear"></div> </div> </div> <div id="yi0wqg2" class="product-maincon"> <div id="0wogwwo" class="product-maincon-in"> <style> .info_tab .cur_tab a{ cursor:auto; } </style> <div id="8aim0wo" class="info_tab"> <div id="w8qk00g" class="info_tab_in"> <ul class="clearfix"> <li id="su0esuy" class="cur_tab" data-tab="249139"><a href="javascript:void(0)">產(chǎn)品詳細</a></li> </ul> </div> </div> <div id="s8ucw0w" class="product-descons"> <div id="c8kcuao" class="descon_item" id="Tabitem249139"><p style="font-size: medium;white-space: normal"><strong><span style="font-family: 宋體;font-size: 21px"><span style="font-family:宋體">石灰</span></span></strong><strong><span style="font-family: Calibri;font-size: 21px">(</span></strong><strong><span style="font-family: 宋體;font-size: 21px"><span style="font-family:宋體">石</span></span></strong><strong><span style="font-family: Calibri;font-size: 21px">)-</span></strong><strong><span style="font-family: 宋體;font-size: 21px"><span style="font-family:宋體">石膏法</span></span></strong><strong></strong></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><strong><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">概述</span></span></strong><strong></strong></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">石灰</span></span><span style="font-family: Calibri;font-size: 19px">(</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">石</span></span><span style="font-family: Calibri;font-size: 19px">)-</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">石膏法脫硫技術(shù)，是目前應用最廣泛、工藝技術(shù)最成熟的標準脫硫工藝技術(shù)。采用廉價(jià)易得的石灰（石）作為脫硫吸收劑，將石灰劑制作成粉末與水混合攪拌成漿液。在吸收塔內，吸收漿液與煙氣接觸混合，煙氣中的二氧化硫與漿液及鼓入的氧化空氣進(jìn)行化學(xué)反應被脫除，最終反應產(chǎn)物為石膏。脫硫后的煙氣經(jīng)除霧器除去帶出的細小液滴。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><strong><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">反應過(guò)程</span></span></strong><strong></strong></p><p style="font-size: medium;white-space: normal"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">石灰</span></span><span style="font-family: 宋體;font-size: 19px">-</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">石膏法脫硫原理</span></span></p><p style="font-size: medium;white-space: normal"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">吸收</span></span><span style="font-family: 宋體;font-size: 19px">SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2 </span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">：</span></span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub"> </span></sub><span style="font-family: 宋體;font-size: 19px">SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">+H</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">O</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">→</span></span><span style="font-family: 宋體;font-size: 19px">H</span><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">+</span></sup><span style="font-family: 宋體;font-size: 19px">+HS0</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">-</span></sup><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">→</span></span><span style="font-family: 宋體;font-size: 19px">H</span><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">+</span></sup><span style="font-family: 宋體;font-size: 19px">+SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">2-</span></sup></p><p style="font-size: medium;white-space: normal"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">溶解：</span></span><span style="font-family: 宋體;font-size: 19px"> Ca(OH)</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">→</span></span><span style="font-family: 宋體;font-size: 19px">Ca</span><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">2+</span></sup><span style="font-family: 宋體;font-size: 19px">+2OH</span><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">-</span></sup><sup></sup></p><p style="font-size: medium;white-space: normal"><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super"> </span></sup><span style="font-family: 宋體;font-size: 19px">CaSO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">→</span></span><span style="font-family: 宋體;font-size: 19px">Ca</span><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">2+</span></sup><span style="font-family: 宋體;font-size: 19px">+SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">2-</span></sup></p><p style="font-size: medium;white-space: normal"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">中和：</span></span><span style="font-family: 宋體;font-size: 19px"> OH</span><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">-</span></sup><span style="font-family: 宋體;font-size: 19px">+H</span><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">+</span></sup><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">→</span></span><span style="font-family: 宋體;font-size: 19px">H</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">O</span></p><p style="font-size: medium;white-space: normal"><span style="font-family: 宋體;font-size: 19px"> OH</span><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">-</span></sup><span style="font-family: 宋體;font-size: 19px">+HSO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">-</span></sup><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">→</span></span><span style="font-family: 宋體;font-size: 19px">SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">2-</span></sup><span style="font-family: 宋體;font-size: 19px">+H</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">O</span></p><p style="font-size: medium;white-space: normal"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">氧化：</span></span><span style="font-family: 宋體;font-size: 19px"> HSO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">-</span></sup><span style="font-family: 宋體;font-size: 19px">+1/2O</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">→</span></span><span style="font-family: 宋體;font-size: 19px">SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">2-</span></sup><span style="font-family: 宋體;font-size: 19px">+H</span><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">+</span></sup></p><p style="font-size: medium;white-space: normal"><span style="font-family: 宋體;font-size: 19px"> SO</span><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">2-</span></sup><span style="font-family: 宋體;font-size: 19px">+1/2O</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">→</span></span><span style="font-family: 宋體;font-size: 19px">SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">4</span></sub><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">2-</span></sup></p><p style="font-size: medium;white-space: normal"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">結晶：</span></span><span style="font-family: 宋體;font-size: 19px"> Ca</span><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">2</span></sup><span style="font-family: 宋體;font-size: 19px">+SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">2-</span></sup><span style="font-family: 宋體;font-size: 19px">+1/2H</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">O</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">→</span></span><span style="font-family: 宋體;font-size: 19px">CaSO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">·</span></span><span style="font-family: 宋體;font-size: 19px">1/2H</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">O</span></p><p style="font-size: medium;white-space: normal"><span style="font-family: 宋體;font-size: 19px"> Ca</span><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">2</span></sup><span style="font-family: 宋體;font-size: 19px">+SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">4</span></sub><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">2-</span></sup><span style="font-family: 宋體;font-size: 19px">+2H</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">O</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">→</span></span><span style="font-family: 宋體;font-size: 19px">CaSO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">4</span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">·</span></span><span style="font-family: 宋體;font-size: 19px">2H</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">O</span></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><span style="font-family: Calibri;font-size: 19px"> </span></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><strong><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">工藝特點(diǎn)</span></span></strong><strong></strong></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><span style="font-family: Calibri;font-size: 19px">1.</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">采用價(jià)廉易得的石灰作為吸收劑，能夠有效地控制運行成本。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><span style="font-family: Calibri;font-size: 19px">2.</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">技術(shù)成熟，脫硫效率高。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><span style="font-family: Calibri;font-size: 19px">3.</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">對工況負荷適應性和</span></span><span style="font-family: Calibri;font-size: 19px">SO2</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">濃度的變化有很好的適用性。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><span style="font-family: Calibri;font-size: 19px">4.</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">副產(chǎn)物為純度較高的石膏，副產(chǎn)物產(chǎn)出可具有一定的價(jià)值。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><strong><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">系統組成</span></span></strong><strong></strong></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">脫硫系統主要包括煙氣系統、石灰漿液制備系統、吸收氧化系統、副產(chǎn)物處理系統、公共系統、電氣控制系統等幾部分組成。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">煙氣系統：包含煙道、煙道加強、煙道支架、煙道膨脹節、檢修排空口及煙道配套的保溫、防腐及爬梯平臺等。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">石灰漿液制備系統：包含石灰儲倉、石灰漿液制備、石灰漿液儲備及配套的攪拌、輸送泵系統等。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">吸收氧化系統：主要包括吸收塔、噴淋層、除霧器、循環(huán)泵、擾動(dòng)設備和氧化風(fēng)機等設備。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">副產(chǎn)物處理系統：石膏排出設備、壓濾機系統、沖洗系統及石膏庫等。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">公共系統：包含工藝水系統、壓縮空氣系統、事故漿液系統。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">電氣控制系統：</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">電氣部分：供配電系統、電氣控制與保護、照明及檢修系統、接地系統、通訊系統、電纜和電纜構筑物、電氣設備布置等。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">控制部分：</span></span><span style="font-family: Calibri;font-size: 19px">DCS</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">控制柜、工控機、</span></span><span style="font-family: Calibri;font-size: 19px">UPS</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">電源、儀表等。</span></span></p><p> <strong style="font-size: medium; text-indent: 37px;"><span style="font-family: 宋體;font-size: 19px">我公司石灰</span></strong><strong style="font-size: medium; text-indent: 37px;"><span style="font-family: Calibri;font-size: 19px">(</span></strong><strong style="font-size: medium; text-indent: 37px;"><span style="font-family: 宋體;font-size: 19px">石</span></strong><strong style="font-size: medium; text-indent: 37px;"><span style="font-family: Calibri;font-size: 19px">)-</span></strong><strong style="font-size: medium; text-indent: 37px;"><span style="font-family: 宋體;font-size: 19px">石膏法技術(shù)特點(diǎn)</span></strong></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><strong></strong></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><span style="font-family: Calibri;line-height: 28px;font-size: 19px">1.</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">優(yōu)化煙道布置，合理設計煙氣流速，盡可能縮短凈煙道長(cháng)度，在煙道內設置導流板、排凝裝置等措施，減小脫硫系統煙道阻力和故障點(diǎn)，為主機長(cháng)期可靠運行打下基礎。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><span style="font-family: Calibri;line-height: 28px;font-size: 19px">2.</span><span style="font-family: 宋體;line-height: 24px;font-size: 16px"> </span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">煙氣入口設計向下傾斜一定的角度，從而使得煙氣進(jìn)吸收塔漩渦區的面積減少。入口角度的合理傾斜將有利噴淋塔內煙氣流態(tài)均勻，煙氣流速均布在</span></span><span style="font-family: Calibri;line-height: 28px;font-size: 19px">3.5</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">～</span></span><span style="font-family: Calibri;line-height: 28px;font-size: 19px">4.0m/s</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">，從而提高脫硫效率。并且設計對噴噴淋，降低來(lái)脫硫塔煙氣溫度，保證煙氣溫度對脫硫塔防腐和內件沒(méi)有損壞。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><span style="font-family: Calibri;line-height: 28px;font-size: 19px">3.</span><span style="font-family: 宋體;line-height: 24px;font-size: 16px"> </span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">噴淋層優(yōu)化設計，每層噴淋層相互交叉，層與層之間噴淋母管軸線(xiàn)夾角約</span></span><span style="font-family: Calibri;line-height: 28px;font-size: 19px">20</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">°，噴淋覆蓋率達</span></span><span style="font-family: Calibri;line-height: 28px;font-size: 19px">200%</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">以上，避免煙氣竄氣。避免局部高溫，保證塔內所有位置氣體達到飽和。塔周邊采用</span></span><span style="font-family: Calibri;line-height: 28px;font-size: 19px">90</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">高效實(shí)心噴嘴，其余采用</span></span><span style="font-family: Calibri;line-height: 28px;font-size: 19px">120</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">空心噴嘴，液滴平均直徑</span></span><span style="font-family: Calibri;line-height: 28px;font-size: 19px">2000</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">微米，具有氣</span></span><span style="font-family: Calibri;line-height: 28px;font-size: 19px">/</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">液接觸充分、脫硫率更高、液氣比更低的特點(diǎn)。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><span style="font-family: Calibri;font-size: 19px">4.</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">在吸收塔內設布氣裝置，與密集型噴淋聯(lián)合使用能有效防止煙氣爬壁短路，改善靠近塔壁的氣液接觸，使氣</span></span><span style="font-family: Calibri;font-size: 19px">/</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">液分布更均勻并將壁上漿液再次引入噴淋區。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><span style="font-family: Calibri;line-height: 28px;font-size: 19px">5.</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">防止塔內結垢及堵塞是吸收塔安全運行的關(guān)鍵。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">本工程采用先進(jìn)可靠的單回路噴淋空塔，逆流煙氣洗滌，吸收塔內氣液接觸區無(wú)填料構件，不設置任何隔柵、托盤(pán)，可有效降低塔內運行阻力，有效杜絕塔內堵塞結垢現象，因此能保證吸收塔長(cháng)期穩定運行。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">設計循環(huán)池停留時(shí)間不低于</span></span><span style="font-family: Calibri;line-height: 28px;font-size: 19px">12h</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">，降低塔內脫硫漿液濃度。如此可大大降低塔內外磨損，避免塔內結垢堵塞，且同樣的液氣比下可提高脫硫效率，確保系統安全穩定運行。</span></span></p><p style="font-size: medium;white-space: normal"><strong><span style="font-family: 宋體;font-size: 21px"><span style="font-family:宋體">雙堿法</span></span></strong><strong></strong></p><p style="font-size: medium;white-space: normal;text-indent: 37px"><strong><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">概述</span></span></strong><strong></strong></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">雙堿法脫硫技術(shù)是采用鈉基脫硫劑進(jìn)行塔內脫硫，由于鈉基脫硫劑堿性強，吸收二氧化硫后反應產(chǎn)物溶解度大，不會(huì )造成過(guò)飽和結晶和結晶結垢堵塞問(wèn)題。另一方面脫硫產(chǎn)物被排入再生池內用氫氧化鈣進(jìn)行還原，再生出的鈉基脫硫劑再被打回脫硫塔循環(huán)使用。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><strong><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">雙堿法脫硫原理</span></span></strong><strong></strong></p><p style="font-size: medium;white-space: normal;margin-left: 48px"><span style="font-family: 宋體;font-size: 19px">1、 </span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">脫硫過(guò)程：</span></span></p><p style="font-size: medium;text-indent: 0;white-space: normal;margin-left: 48px"><span style="font-family: 宋體;font-size: 19px">Na</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">CO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><span style="font-family: 宋體;font-size: 19px">+SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">→</span></span><span style="font-family: 宋體;font-size: 19px">Na</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><span style="font-family: 宋體;font-size: 19px">+CO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">↑</span></span><span style="font-family: 宋體;font-size: 19px"> (1)</span></p><p style="font-size: medium;text-indent: 0;white-space: normal;margin-left: 48px"><span style="font-family: 宋體;font-size: 19px">2NaOH+SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">→</span></span><span style="font-family: 宋體;font-size: 19px">Na</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><span style="font-family: 宋體;font-size: 19px">+H</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">O (2)</span></p><p style="font-size: medium;text-indent: 0;white-space: normal;margin-left: 48px"><span style="font-family: 宋體;font-size: 19px">Na</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><span style="font-family: 宋體;font-size: 19px">+SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">+H</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">O</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">→</span></span><span style="font-family: 宋體;font-size: 19px">2NaHSO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3 </span></sub><span style="font-family: 宋體;font-size: 19px">(3)</span></p><p style="font-size: medium;text-indent: 0;white-space: normal;margin-left: 48px"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">以上三式視吸收液酸堿度不同而異：（</span></span><span style="font-family: 宋體;font-size: 19px">1</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">）式為吸收啟動(dòng)反應式；堿性較高時(shí)（</span></span><span style="font-family: 宋體;font-size: 19px">PH>9</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">），（</span></span><span style="font-family: 宋體;font-size: 19px">2</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">）式為主要反應；堿性降低時(shí)到中性甚至酸性時(shí)（</span></span><span style="font-family: 宋體;font-size: 19px">5<PH<9</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">），則按（</span></span><span style="font-family: 宋體;font-size: 19px">3</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">）式發(fā)生反應。</span></span></p><p style="font-size: medium;white-space: normal;margin-left: 48px"><span style="font-family: 宋體;font-size: 19px">2、 </span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">再生過(guò)程：</span></span></p><p style="font-size: medium;text-indent: 0;white-space: normal;margin-left: 48px"><span style="font-family: 宋體;font-size: 19px">2NaHSO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><span style="font-family: 宋體;font-size: 19px">+Ca(OH)</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">→</span></span><span style="font-family: 宋體;font-size: 19px">Na</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><span style="font-family: 宋體;font-size: 19px">+CaSO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">↓</span></span><span style="font-family: 宋體;font-size: 19px">+2H</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">O (4)</span></p><p style="font-size: medium;text-indent: 0;white-space: normal;margin-left: 48px"><span style="font-family: 宋體;font-size: 19px">Na</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px">SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><span style="font-family: 宋體;font-size: 19px">+Ca(OH)</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">→</span></span><span style="font-family: 宋體;font-size: 19px">2NaOH+CaSO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">↓</span></span><span style="font-family: 宋體;font-size: 19px"> (5)</span></p><p style="font-size: medium;text-indent: 0;white-space: normal;margin-left: 48px"><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">在石灰漿液（石灰達到過(guò)飽和狀況）中，中性（兩性）的</span></span><span style="font-family: 宋體;font-size: 19px">NaHSO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">很快跟石灰反應從而釋放出</span></span><span style="font-family: 宋體;font-size: 19px">[Na</span><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">+</span></sup><span style="font-family: 宋體;font-size: 19px">]</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">，隨后生成的</span></span><span style="font-family: 宋體;font-size: 19px">[SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">3</span></sub><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">2-</span></sup><span style="font-family: 宋體;font-size: 19px">]</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">又繼續跟石灰反應，反應生成的亞硫酸鈣以半水化合物形式慢慢沉淀下來(lái)，從而使</span></span><span style="font-family: 宋體;font-size: 19px">[Na</span><sup><span style="font-family: 宋體;font-size: 19px;vertical-align: super">+</span></sup><span style="font-family: 宋體;font-size: 19px">]</span><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">得到再生，吸收液恢復對</span></span><span style="font-family: 宋體;font-size: 19px">SO</span><sub><span style="font-family: 宋體;font-size: 19px;vertical-align: sub">2</span></sub><span style="font-family: 宋體;font-size: 19px"><span style="font-family:宋體">的吸收能力，循環(huán)使用。</span></span><strong style="text-indent: 37px;"><span style="font-family: Calibri;line-height: 28px;font-size: 19px"> </span></strong></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><strong><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">系統組成</span></span></strong><strong></strong></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">主要包括煙氣系統、吸收劑制備系統、</span></span><span style="font-family: Calibri;line-height: 28px;font-size: 19px">SO2</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">吸收系統、再生系統、石膏脫水處理系統、電氣控制系統。</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><strong><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">工藝特點(diǎn)</span></span></strong><strong></strong></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><span style="font-family: Calibri;line-height: 28px;font-size: 19px">1.</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">鈉基作為吸收液，避免了結垢；</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><span style="font-family: Calibri;line-height: 28px;font-size: 19px">2.</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">鈉基吸收速率高，較低的液氣比，較高的脫硫效率；</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><span style="font-family: Calibri;line-height: 28px;font-size: 19px">3.</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">系統占地規模較小，投資較低；</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><span style="font-family: Calibri;line-height: 28px;font-size: 19px">4.</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">再生和沉淀分離在塔外進(jìn)行，大大降低塔內和管道內的結垢機會(huì )；</span></span></p><p style="font-size: medium;white-space: normal;text-indent: 37px;line-height: 1.5px"><span style="font-family: Calibri;line-height: 28px;font-size: 19px">5.</span><span style="font-family: 宋體;line-height: 28px;font-size: 19px"><span style="font-family:宋體">石灰作為再生劑，為主要實(shí)際消耗物，鈉堿消耗較少，相比單堿法運行成本較低。<br/><br/></span></span></p><p><br/></p></div> </div><div id="k80wo0q" class="news-others"> <div id="gcukmyw" class="pre-next" > <div id="ec0og8g" class="news-prev"> 上一個(gè)： <a href="/product-46128-113146.html">煙氣脫白</a> </div> <div id="g8kcg0y" class="news-next"> 下一個(gè)： <a href="/product-46128-113212.html">脫硫</a> </div> </div> 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